IMAT 2023 · Question 58

Q58 - Changes of state and latent heat

A metal jug of negligible thermal capacity contains a mass M of water at a temperature T₁. A dry block of ice (specific latent heat of fusion = Lf) of mass m at 0 °C is dropped into the water (specific heat capacity = c) and begins to melt. At thermal equilibrium, there is no ice in the jug and the temperature of all the water is T₂. There is no thermal energy transfer between the atmosphere and the water or between the atmosphere and the ice. Which expression is used to calculate m? A) Mc(T₁ − T₂) / Lf B) McT₁ / Lf C) McT₁ / (Lf + cT₂) D) Mc(T₁ − T₂) / (Lf + cT₂) E) Mc(T₁ − T₂) / (Lf + cT₁)
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The correct answer is D) Mc(T₁ − T₂) / (Lf + cT₂).

No heat is lost, so the heat given out by the warm water equals the heat taken in by the ice.

  • Water cooling from T₁ to T₂: Mc(T₁ − T₂)

  • Ice melting at 0 °C: mLf

  • The melted ice warming from 0 to T₂: mcT₂

So Mc(T₁ − T₂) = m(Lf + cT₂), which gives m = Mc(T₁ − T₂)/(Lf + cT₂).

Option A forgets that the meltwater also has to warm up.

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