IMAT 2026 · Question 42
Q42 - States of matter
The correct answer is A) The intermolecular forces in A are stronger than those in B.
When a liquid boils, its molecules separate from each other, but the molecules themselves stay intact: steam is still H₂O. So boiling only overcomes the intermolecular forces (hydrogen bonds, dipole–dipole, London forces). The stronger they are, the higher the boiling point.
Example: H₂O (100 °C) and H₂S (about −60 °C) have similar shapes, but water forms hydrogen bonds.
A) Correct: Stronger intermolecular forces mean a higher boiling point.
B) Incorrect: Intramolecular forces (covalent bonds inside the molecule) are not broken during boiling.
C) Incorrect: Weaker forces would give a lower boiling point.
D) Incorrect: Same mistake as B: bonds inside the molecule do not decide the boiling point.
E) Incorrect: Weaker intermolecular forces in A would give A the lower boiling point.
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