IMAT 2026 · Question 42

Q42 - States of matter

Substance A has a higher boiling point than Substance B if: A) The intermolecular forces in A are stronger than those in B B) The intramolecular forces in A are stronger than those in B C) The intermolecular forces in A are weaker than those in B D) The intramolecular forces in A are weaker than those in B E) The intramolecular forces in A are stronger than those in B, but the intermolecular forces in A are weaker than those in B
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The correct answer is A) The intermolecular forces in A are stronger than those in B.

When a liquid boils, its molecules separate from each other, but the molecules themselves stay intact: steam is still H₂O. So boiling only overcomes the intermolecular forces (hydrogen bonds, dipole–dipole, London forces). The stronger they are, the higher the boiling point.

Example: H₂O (100 °C) and H₂S (about −60 °C) have similar shapes, but water forms hydrogen bonds.

A) Correct: Stronger intermolecular forces mean a higher boiling point.

B) Incorrect: Intramolecular forces (covalent bonds inside the molecule) are not broken during boiling.

C) Incorrect: Weaker forces would give a lower boiling point.

D) Incorrect: Same mistake as B: bonds inside the molecule do not decide the boiling point.

E) Incorrect: Weaker intermolecular forces in A would give A the lower boiling point.

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