IMAT 2025 · Question 43

Q43 - Aromatic hydrocarbons

In benzene: A) all the carbon atoms are sp³ hybridized and the molecule has a planar structure B) all the carbon atoms are sp² hybridized and the molecule has a planar structure C) all the carbon atoms are sp hybridized D) three carbon atoms are sp³ hybridized and three atoms are sp² hybridized E) all the carbon atoms are sp² hybridized and the molecule has a chair or boat structure
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The correct answer is B) all the carbon atoms are sp² hybridized and the molecule has a planar structure.

Every carbon in benzene is sp², with 120° angles, so the molecule is flat. The leftover p orbitals on each carbon overlap above and below the ring to form the delocalised π system.

Chair and boat shapes (E) belong to cyclohexane, where the carbons are sp³.

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